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What are the various factors due to which the ionization enthalpy of the main group elements tends to decrease down a group?

Class: Class 12 Subject: Chemistry Topic: Basics Of Class 12th Chemistry

The following are the causes that cause the ionisation enthalpy of the primary group elements to fall along a group:

(i) Elements' atomic sizes grow larger: The number of shells grows as we proceed down a group. As a result, as you move down a group, the atomic size gradually increases. The valence electrons are not held as tightly when the distance between them and the nucleus grows. As a result, they can be simply removed. As a result, as you move down a group, the ionisation energy diminishes.

(ii) Shielding effect: As you move down a group, the number of electrons in their inner shells grows. As a result, the inner core electrons protect the valence electrons from the nucleus as they go along a group. As a result, the nucleus does not hold the valence electrons particularly tightly. As a result, the energy required to remove a valence electron reduces as the group number increases.

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