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The following are the causes that cause the ionisation enthalpy of
the primary group elements to fall along a group:
(i) Elements' atomic sizes grow larger: The number of shells grows
as we proceed down a group. As a result, as you move down a group, the atomic
size gradually increases. The valence electrons are not held as tightly when
the distance between them and the nucleus grows. As a result, they can be
simply removed. As a result, as you move down a group, the ionisation energy
diminishes.
(ii) Shielding effect: As you move down a group, the number of
electrons in their inner shells grows. As a result, the inner core electrons
protect the valence electrons from the nucleus as they go along a group. As a
result, the nucleus does not hold the valence electrons particularly tightly.
As a result, the energy required to remove a valence electron reduces as the
group number increases.
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